562 transportation accidents,which of dangerous chemicals from 2013 to 2014 in China,were analyzed, Statistical analysis was carried out from the following aspects: accident road segment, classification of dangerous chemicals, the reason and occurrence time of the accident, and so on. The results show that: the proportion of accidents in the normal section is the highest, accounting for 54%,the statistics of reason show that the proportion of accidents caused by traffic accidents is higher than non-traffic accidents. From March to August each year and from 8 to 9 o 'clock every day is the peak time of the dangerous chemical transportation accident. Finally, some countermeasures and suggestions, based on the analysis of the statistical results, were put forward to reduce the transportation accidents of dangerous chemicals in China.